![]() Because shifts in binding and absorption energies are less pronounced, other features such as lineshape and satellite intensity become important in the determination of relative charges and valence states. ![]() In this chapter, these spectroscopic techniques are applied to various transition-metal phosphides, arsenides, and antimonides, including a diverse class of compounds based on the MnP-type structure, as well as some binary and ternary skutterudites. However, interpretation of these spectra is more difficult for compounds with significant covalent bonding character. X-ray photoelectron spectroscopy and related techniques such as X-ray absorption spectroscopy provide useful information about the electronic structure and bonding of inorganic solids.
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